Conducting and Magnetic Organometallic Molecular Materials: - download pdf or read online

By Marc Fourmigué,Lahcène Ouahab

For a number of years, the 2 parallel worlds of Molecular Conductors in a single hand and Molecular Magnetism within the different have grown facet via facet, the previous basically in line with radical natural molecules, the latter primarily in response to the excessive spin homes of steel complexes. over the past few years in spite of the fact that, organometallic derivatives have began to play an more and more very important function in either worlds, and feature in lots of methods contributed to open a number of passages among those worlds. This quantity acknowledges this crucial rising evolution of either learn parts. it's not meant to provide a finished view of all attainable organometallic fabrics, and polymers for instance weren't thought of right here. really we current a variety of the latest learn issues the place organometallic derivatives have been proven to play a very important function within the environment of accomplishing and/or magnetic homes in crystalline fabrics. First, the function of organometallic anions in tet- thiafulvalenium-based molecular conductors is highlighted by way of Schlueter, whereas Kubo and Kato describe very fresh ortho-metalated chelating ligands appended to the TTF middle and their carrying out salts. the mix of accomplishing and magnetic houses and the hunt for p–d interactions are analyzed in comp- mentary contributions via Myazaki and Ouahab, whereas Valade makes a speciality of the single classification of steel bis(dithiolene) complexes to provide upward thrust to superconductive molecular fabrics, in organization with natural in addition to organometallic cations.

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Conducting and Magnetic Organometallic Molecular Materials: 27 (Topics in Organometallic Chemistry) by Marc Fourmigué,Lahcène Ouahab

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